Vacuum-Deposited Poly(o-phenylenediamine)/WO3•nH2O Nanocomposite Thin Film for NO2 Gas Sensor
Identifieur interne : 000C64 ( Chine/Analysis ); précédent : 000C63; suivant : 000C65Vacuum-Deposited Poly(o-phenylenediamine)/WO3•nH2O Nanocomposite Thin Film for NO2 Gas Sensor
Auteurs : RBID : Pascal:09-0452057Descripteurs français
- Pascal (Inist)
- Nanocomposite, Aniline dérivé polymère, Polymère hétérocyclique azote, Polymère échelle, Polymère aromatique, Cyclopolymère, Tungstène VI Oxyde, Couche mince, Couche ITO, Détecteur de gaz, Fabrication, Dépôt sous vide, Morphologie, Absorption optique, Sensibilité, Temps réponse, Dioxyde d'azote, Stabilité stockage, Etude expérimentale.
English descriptors
- KwdEn :
- Aniline derivative polymer, Aromatic polymer, Cyclopolymer, Experimental study, Gas detector, ITO layers, Ladder polymer, Manufacturing, Morphology, Nanocomposite, Nitrogen dioxide, Nitrogen heterocycle polymer, Optical absorption, Response time, Sensitivity, Storage stability, Thin film, Tungsten VI Oxides, Vacuum deposition.
Abstract
The vacuum-deposited thin film of hydrated tungsten oxide (WO3•nH2O) embedded poly(o-phenylenediamine) (PoPD/ WO3•nH2O) nanocomposite was fabricated on an indium tin oxide (ITO) coated glass surface for potential NO2 gas sensor application. The resulting PoPD/WO3•nHO/ITO thin film was characterized using ultraviolet-visible spectroscopy (UV-vis), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD), and electron microscopy (SEM). The composite thin film exhibited a crystalline surface morphology containing nanocrystalls of WO3•nH2O with a diameter ranging from 5 to 10nm. The PoPD/WO3•nH2O/ITO film allowed for the low potential detection of NO2 gas at concentration range from 0 to 1800 ppm. The NO2 gas sensing characteristics were studied by measuring change in the current with respect to concentration and time. The current of the PoPD/WO3•nH2O/ITO film was linearly increased with an increase in concentration of NO2 gas with a response of ∼9 s.
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Pascal:09-0452057Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Vacuum-Deposited Poly(o-phenylenediamine)/WO<sub>3</sub>
•nH<sub>2</sub>
O Nanocomposite Thin Film for NO<sub>2</sub>
Gas Sensor</title>
<author><name sortKey="Tiwari, Ashutosh" uniqKey="Tiwari A">Ashutosh Tiwari</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Division of Engineering Materials, National Physical Laboratory, Dr. K. S. Krishnan Marg</s1>
<s2>New Delhi 110012</s2>
<s3>IND</s3>
<sZ>1 aut.</sZ>
</inist:fA14>
<country>Inde</country>
<wicri:noRegion>New Delhi 110012</wicri:noRegion>
</affiliation>
</author>
<author><name>SONGJUN LI</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University</s1>
<s2>Wuhan 430079</s2>
<s3>CHN</s3>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<wicri:noRegion>Wuhan 430079</wicri:noRegion>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="inist">09-0452057</idno>
<date when="2009">2009</date>
<idno type="stanalyst">PASCAL 09-0452057 INIST</idno>
<idno type="RBID">Pascal:09-0452057</idno>
<idno type="wicri:Area/Main/Corpus">004E63</idno>
<idno type="wicri:Area/Main/Repository">004858</idno>
<idno type="wicri:Area/Chine/Extraction">000C64</idno>
</publicationStmt>
<seriesStmt><idno type="ISSN">0032-3896</idno>
<title level="j" type="abbreviated">Polym. j.</title>
<title level="j" type="main">Polymer journal</title>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aniline derivative polymer</term>
<term>Aromatic polymer</term>
<term>Cyclopolymer</term>
<term>Experimental study</term>
<term>Gas detector</term>
<term>ITO layers</term>
<term>Ladder polymer</term>
<term>Manufacturing</term>
<term>Morphology</term>
<term>Nanocomposite</term>
<term>Nitrogen dioxide</term>
<term>Nitrogen heterocycle polymer</term>
<term>Optical absorption</term>
<term>Response time</term>
<term>Sensitivity</term>
<term>Storage stability</term>
<term>Thin film</term>
<term>Tungsten VI Oxides</term>
<term>Vacuum deposition</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Nanocomposite</term>
<term>Aniline dérivé polymère</term>
<term>Polymère hétérocyclique azote</term>
<term>Polymère échelle</term>
<term>Polymère aromatique</term>
<term>Cyclopolymère</term>
<term>Tungstène VI Oxyde</term>
<term>Couche mince</term>
<term>Couche ITO</term>
<term>Détecteur de gaz</term>
<term>Fabrication</term>
<term>Dépôt sous vide</term>
<term>Morphologie</term>
<term>Absorption optique</term>
<term>Sensibilité</term>
<term>Temps réponse</term>
<term>Dioxyde d'azote</term>
<term>Stabilité stockage</term>
<term>Etude expérimentale</term>
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<front><div type="abstract" xml:lang="en">The vacuum-deposited thin film of hydrated tungsten oxide (WO<sub>3</sub>
•nH<sub>2</sub>
O) embedded poly(o-phenylenediamine) (PoPD/ WO<sub>3</sub>
•nH<sub>2</sub>
O) nanocomposite was fabricated on an indium tin oxide (ITO) coated glass surface for potential NO<sub>2</sub>
gas sensor application. The resulting PoPD/WO<sub>3</sub>
•nHO/ITO thin film was characterized using ultraviolet-visible spectroscopy (UV-vis), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD), and electron microscopy (SEM). The composite thin film exhibited a crystalline surface morphology containing nanocrystalls of WO<sub>3</sub>
•nH<sub>2</sub>
O with a diameter ranging from 5 to 10nm. The PoPD/WO<sub>3</sub>
•nH<sub>2</sub>
O/ITO film allowed for the low potential detection of NO<sub>2</sub>
gas at concentration range from 0 to 1800 ppm. The NO<sub>2</sub>
gas sensing characteristics were studied by measuring change in the current with respect to concentration and time. The current of the PoPD/WO<sub>3</sub>
•nH<sub>2</sub>
O/ITO film was linearly increased with an increase in concentration of NO<sub>2</sub>
gas with a response of ∼9 s.</div>
</front>
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•nH<sub>2</sub>
O Nanocomposite Thin Film for NO<sub>2</sub>
Gas Sensor</s1>
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<fA14 i1="01"><s1>Division of Engineering Materials, National Physical Laboratory, Dr. K. S. Krishnan Marg</s1>
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<s3>IND</s3>
<sZ>1 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>The vacuum-deposited thin film of hydrated tungsten oxide (WO<sub>3</sub>
•nH<sub>2</sub>
O) embedded poly(o-phenylenediamine) (PoPD/ WO<sub>3</sub>
•nH<sub>2</sub>
O) nanocomposite was fabricated on an indium tin oxide (ITO) coated glass surface for potential NO<sub>2</sub>
gas sensor application. The resulting PoPD/WO<sub>3</sub>
•nHO/ITO thin film was characterized using ultraviolet-visible spectroscopy (UV-vis), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD), and electron microscopy (SEM). The composite thin film exhibited a crystalline surface morphology containing nanocrystalls of WO<sub>3</sub>
•nH<sub>2</sub>
O with a diameter ranging from 5 to 10nm. The PoPD/WO<sub>3</sub>
•nH<sub>2</sub>
O/ITO film allowed for the low potential detection of NO<sub>2</sub>
gas at concentration range from 0 to 1800 ppm. The NO<sub>2</sub>
gas sensing characteristics were studied by measuring change in the current with respect to concentration and time. The current of the PoPD/WO<sub>3</sub>
•nH<sub>2</sub>
O/ITO film was linearly increased with an increase in concentration of NO<sub>2</sub>
gas with a response of ∼9 s.</s0>
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