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Vacuum-Deposited Poly(o-phenylenediamine)/WO3•nH2O Nanocomposite Thin Film for NO2 Gas Sensor

Identifieur interne : 000C64 ( Chine/Analysis ); précédent : 000C63; suivant : 000C65

Vacuum-Deposited Poly(o-phenylenediamine)/WO3•nH2O Nanocomposite Thin Film for NO2 Gas Sensor

Auteurs : RBID : Pascal:09-0452057

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English descriptors

Abstract

The vacuum-deposited thin film of hydrated tungsten oxide (WO3•nH2O) embedded poly(o-phenylenediamine) (PoPD/ WO3•nH2O) nanocomposite was fabricated on an indium tin oxide (ITO) coated glass surface for potential NO2 gas sensor application. The resulting PoPD/WO3•nHO/ITO thin film was characterized using ultraviolet-visible spectroscopy (UV-vis), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD), and electron microscopy (SEM). The composite thin film exhibited a crystalline surface morphology containing nanocrystalls of WO3•nH2O with a diameter ranging from 5 to 10nm. The PoPD/WO3•nH2O/ITO film allowed for the low potential detection of NO2 gas at concentration range from 0 to 1800 ppm. The NO2 gas sensing characteristics were studied by measuring change in the current with respect to concentration and time. The current of the PoPD/WO3•nH2O/ITO film was linearly increased with an increase in concentration of NO2 gas with a response of ∼9 s.

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Pascal:09-0452057

Le document en format XML

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<title xml:lang="en" level="a">Vacuum-Deposited Poly(o-phenylenediamine)/WO
<sub>3</sub>
•nH
<sub>2</sub>
O Nanocomposite Thin Film for NO
<sub>2</sub>
Gas Sensor</title>
<author>
<name sortKey="Tiwari, Ashutosh" uniqKey="Tiwari A">Ashutosh Tiwari</name>
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<s1>Division of Engineering Materials, National Physical Laboratory, Dr. K. S. Krishnan Marg</s1>
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<s3>IND</s3>
<sZ>1 aut.</sZ>
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<country>Inde</country>
<wicri:noRegion>New Delhi 110012</wicri:noRegion>
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</author>
<author>
<name>SONGJUN LI</name>
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<s1>Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University</s1>
<s2>Wuhan 430079</s2>
<s3>CHN</s3>
<sZ>2 aut.</sZ>
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<country>République populaire de Chine</country>
<wicri:noRegion>Wuhan 430079</wicri:noRegion>
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<term>Morphology</term>
<term>Nanocomposite</term>
<term>Nitrogen dioxide</term>
<term>Nitrogen heterocycle polymer</term>
<term>Optical absorption</term>
<term>Response time</term>
<term>Sensitivity</term>
<term>Storage stability</term>
<term>Thin film</term>
<term>Tungsten VI Oxides</term>
<term>Vacuum deposition</term>
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<div type="abstract" xml:lang="en">The vacuum-deposited thin film of hydrated tungsten oxide (WO
<sub>3</sub>
•nH
<sub>2</sub>
O) embedded poly(o-phenylenediamine) (PoPD/ WO
<sub>3</sub>
•nH
<sub>2</sub>
O) nanocomposite was fabricated on an indium tin oxide (ITO) coated glass surface for potential NO
<sub>2</sub>
gas sensor application. The resulting PoPD/WO
<sub>3</sub>
•nHO/ITO thin film was characterized using ultraviolet-visible spectroscopy (UV-vis), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD), and electron microscopy (SEM). The composite thin film exhibited a crystalline surface morphology containing nanocrystalls of WO
<sub>3</sub>
•nH
<sub>2</sub>
O with a diameter ranging from 5 to 10nm. The PoPD/WO
<sub>3</sub>
•nH
<sub>2</sub>
O/ITO film allowed for the low potential detection of NO
<sub>2</sub>
gas at concentration range from 0 to 1800 ppm. The NO
<sub>2</sub>
gas sensing characteristics were studied by measuring change in the current with respect to concentration and time. The current of the PoPD/WO
<sub>3</sub>
•nH
<sub>2</sub>
O/ITO film was linearly increased with an increase in concentration of NO
<sub>2</sub>
gas with a response of ∼9 s.</div>
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•nH
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O Nanocomposite Thin Film for NO
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•nH
<sub>2</sub>
O) embedded poly(o-phenylenediamine) (PoPD/ WO
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•nH
<sub>2</sub>
O) nanocomposite was fabricated on an indium tin oxide (ITO) coated glass surface for potential NO
<sub>2</sub>
gas sensor application. The resulting PoPD/WO
<sub>3</sub>
•nHO/ITO thin film was characterized using ultraviolet-visible spectroscopy (UV-vis), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD), and electron microscopy (SEM). The composite thin film exhibited a crystalline surface morphology containing nanocrystalls of WO
<sub>3</sub>
•nH
<sub>2</sub>
O with a diameter ranging from 5 to 10nm. The PoPD/WO
<sub>3</sub>
•nH
<sub>2</sub>
O/ITO film allowed for the low potential detection of NO
<sub>2</sub>
gas at concentration range from 0 to 1800 ppm. The NO
<sub>2</sub>
gas sensing characteristics were studied by measuring change in the current with respect to concentration and time. The current of the PoPD/WO
<sub>3</sub>
•nH
<sub>2</sub>
O/ITO film was linearly increased with an increase in concentration of NO
<sub>2</sub>
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